DETERMINATION OF VIBRATIONAL AND ROTATIONAL CONSTANTS IN THE CASE OF A STRONG FERMI RESONANCE APPLICATION TO CO$2$*

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1964

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Ohio State University

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In the case of a strong Fermi resonance, some high order terms may have a very large influence on the values of molecular constants. For instance the $dependence^{1}$ of the Fermi coupling element upon J should not be neglected in computing the inertia constants B. In relation to this effect, the assignment of vibrational levels and the values of vibrational and rotational constants of the molecule $CO_{2}$ will be discussed.

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$^{\ast}$ Supported in part by the Air Force Cambridge Research Laboratories O.A.R. $^{1}$ S. Maes, Chaiers de Physique 14, 125 (1960).
Author Institution: Laboratoire de Spectroscopie Mol$eculaire, Facult$e des Sciences de Paris

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http://hdl.handle.net/1811/14643

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1960-1969