RESONANCE FLUORESCINCE OF $BO_{2}$

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1977

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Ohio State University

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Previous studies of the electronic spectrum of BO2 observed in absorption,1,2 emission3 and by argon ion laser-excited fluorescence4 have revealed that the characterization of the energy levels of this molecule is complicated by the combined effects of spin-orbit coupling, the Renner effect and Fermi resonance. In unraveling these effects it becomes essential to have firmly established vibrational assignments for transitions involving all levels of the various Fermi polyads, for example, the (100,020), (110,030) and (200,120,040) polyads. Rotational analysis may provide the necessary confirmation of vibrational assignments, but it requires considerable effort, and it is not possible in some cases because of low intensity or overlapping structure. In view of these difficulties in the BO2 analysis, we have examined the resonance fluorescence spectra resulting from selective excitation of the levels in the excited state polyads indicated above. Most of these levels were populated by excitation from the 000 X2Πg level of 11BO2 with a nitrogen-pumped dye laser operating between 4891 and 5470 {\AA} with a bandwidth of about 0.4 {\AA}. Our observations provide additional confirmation for most of the vibrational assignments given by Johns,1 and they have resulted in the assignment of more than fifty new transitions involving the 100, 020, 200, 120, 040 levels in both the A2Π and X2Π states of 11BO2. In addition, about five transitions of 10BO2 were observed which confirm the 020 (P=3/2,=0,2) and 100 (P = 3/2) ground state vibronic levels assigned by Dymek.2

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1J.W.C. Johns, Can. J. Phys. 36, 1738 (1961). 2C. J. Dymek, Ph.D. thesis, The Ohio State University (1974). 3B. S. Snowden, Jr., Ph.D. thesis, Vanderbilt University (1962). 4D. K. Russell, et al., Chem. Phys. Lett. 20, 153 (1973).


Author Institution: Department of Chemistry, The Ohio State University

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