LASER SPECTROSCOPY OF $SiF_{2}$ AND CHEMILUMINESCENCE IN REACTIONS WITH FLUORINE ATOMS AND MOLECULES

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1985

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Ohio State University

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The SiF2 radical is an important intermediate in the plasma etching of silicon in fluorocarbon plasmas, a widely used semiconductor device fabrication process. We report tunable dye laser fluorescence and tunable diode laser infrared absorption spectra of SiF2, taken as part of a program of development of laser diagnostics for such processes. We also used these diagnostics in a fast flow reactor to measure the kinetics of SiF2 reactions with F and F2. The chemiluminescence observed during plasma etching has been attributed to these reactions,1 although some doubt remains.2 The similarity in activation engergies for the emission and etching has been used as deciding evidence in a detailed model of the etching process. We will present results on the chemiluminescent spectrum from the reaction of F and F2 with SiF2 formed from two different sources, SiF4 passed over hot Si, and thermal decomposition of Si2F6.

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1J.A. Mucha, D.L. Flamm, and V.M. Donnelly, J. Appl. Phys. 53, 4553 (1982). 2H.F. Winters and F.A. Houle, J. Appl. Phys. 54, 1218 (1983) 3J.A. Mucha, V.M. Donnelly, and D.L. Flamm, J. Phys. Chem. 85, 3529 (1981)


Author Institution: Aerodyne Research, Inc.; Aerodyne Research, Inc.; Aerodyne Research, Inc.; Department of Chemistry, Washington University

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