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dc.creatorCarreira, L. A.en_US
dc.creatorMalloy, Thomas B., Jr.en_US
dc.creatorTowns, T. G.en_US
dc.date.accessioned2006-06-15T13:52:55Z
dc.date.available2006-06-15T13:52:55Z
dc.date.issued1977en_US
dc.identifier1977-FA-3en_US
dc.identifier.urihttp://hdl.handle.net/1811/9970
dc.descriptionT B. Malloy, Jr.: On leave from Departments of Physics and Chemistry, Mississippi State University, Mississippi State, Mississippi.en_US
dc.descriptionAuthor Institution: Department of Chemistry, University of Georgiaen_US
dc.description.abstractThe torsional fundamental of vinyl cyclopropane has been observed in the low-frequency region of the Raman spectrum of a gaseous sample; although strong, the band is broad and no resolvable fine structure is observed. The overtones $(\Delta_\nu = 2)$ of the torsion are considerably weaker but, as expected, consist of a series of sharp Q-branches beginning at 223 $cm^{-1}$ and progressing toward lower frequency with an average spacing of $4.5 cm^{-1}$. Examination of the spectrum in the mid-Raman region has indicated the presence of two rotamers, the most abundant being the s-trans conformer. A study of the temperature dependence of two pairs of bands has yielded a $\Delta H$ of $\sim$ 550 $cm^{-1}$. All of the above data are being used to determine a periodic potential function governing internal rotation in this molecule.en_US
dc.format.extent136639 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleTORSIONAL POTENTIAL FUNCTION FOR VINYLCYCLOPROPANEen_US
dc.typearticleen_US


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