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dc.creatorChao, Robert S.en_US
dc.creatorKhanna, R. K.en_US
dc.date.accessioned2006-06-15T13:52:50Z
dc.date.available2006-06-15T13:52:50Z
dc.date.issued1977en_US
dc.identifier1977-FA-11en_US
dc.identifier.urihttp://hdl.handle.net/1811/9966
dc.descriptionAuthor Institution: Department of Macromolecular Science, Case Western Reserve University; Department of Chemistry, University of Marylanden_US
dc.description.abstractResonance Raman spectra are obtained for iodine in chloroform solution employing a number of exciting frequencies within the electronic absorption region. The excitation profiles (experimental intensity against excitation frequencies) of the fundamental band at 211 $cm^{-1}$ as well as of overtone bands at 422 $cm^{-1}$ and 632 $cm^{-1}$ showed that not only is the peak of the excitation profile consistently shifted but also the corresponding damping value of each profile varies. Theoretical expressions for the frequency dependence of the intensities of Raman lines in rigorous resonance Raman scattering are discussed. In this effort the main contribution to the change in polarizability is obtained from the derivatives of the transition moment with respect to the vibrational normal coordinates instead of the derivatives of the electronic frequency. This leads to excellent agreement between the derived theoretical expressions and the experimental results obtained from the iodine solution.en_US
dc.format.extent136738 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleRIGOROUS RESONANCE RAMAN INTENSITIES OF IODINE SOLUTIONen_US
dc.typearticleen_US


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