SYMMETRIC TOP BEHAVIOR IN THE PERTURBED $^{2}B_{2}$ STATE OF $NO_{2}$
Publisher:
Ohio State UniversityAbstract:
The observed symmetric top properties of fluorescence from the perturbed visible $^{2} B_{2}$ state of $NO_{2}$ are attributed to average behavior of high vibrationally excited perturbing ground state levels. Such attribution precludes assignment of an equilibrium configuration to the perturbed $^{2}B_{2}$ state, except as a weighted average, and possibly explains the considerable variation in effective rotational constants from band to band. A comparison is made with $NH_{2}$.
Description:
Author Institution: Department of Physics, Columbia University
Type:
articleOther Identifiers:
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