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dc.creatorBergeman, T.en_US
dc.creatorCossart, D.en_US
dc.date.accessioned2006-06-15T13:50:25Z
dc.date.available2006-06-15T13:50:25Z
dc.date.issued1976en_US
dc.identifier1976-TN-3en_US
dc.identifier.urihttp://hdl.handle.net/1811/9866
dc.descriptionAuthor Institution: Department of Physics, Fordham University; Laboratoire de Photophysique Mol\'{e}culaire, Universit\'{e} de Paris-Suden_US
dc.description.abstractWe have obtained new high-resolution data on some 25 vibrational levels of the $d^{3}\Delta_{i}, a^{\prime}^{3}\Sigma^{+}, e^{3}\Sigma^{-}, a^{3}\Pi$, and $A^{1}\Pi$ states of CS from uv absorption and emission $spectra.^{1}$ Because of numerous perturbation crossings and substantial perturbation shifts from spin-orbit interactions, the extraction of true ""deperturbed"" parameters has presented a challenge to spectral analysis. We have resorted to fittings to Hamiltonian secular equations of dimension as large as $15 \times 15$, supplemented by second-order perturbation shifts computed from the empirical electronic state interactions. A sensitive test of the accuracy of the parameters of each state and the derived potential curves is whether the off-diagonal spin-orbit perturbation elements are proportional to the computed vibrational overlap integrals. The results which we present are obtained from several stages of iteration and exhibit consistency in most cases.en_US
dc.format.extent128647 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleVALENCE EXCITED STATES OF CS: A STUDY OF EXTENSIVE SPIN-ORBIT PERTURBATIONSen_US
dc.typearticleen_US


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