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dc.creatorPenn, R. E.en_US
dc.creatorOlsen, R. J.en_US
dc.creatorBuxton, L. W.en_US
dc.date.accessioned2006-06-15T13:48:35Z
dc.date.available2006-06-15T13:48:35Z
dc.date.issued1976en_US
dc.identifier1976-Sigma-N-8en_US
dc.identifier.urihttp://hdl.handle.net/1811/9787
dc.descriptionThis research was performed under the auspices of US ERDA.en_US
dc.descriptionAuthor Institution: Department of Chemistry, University of Missourien_US
dc.description.abstractFrom the microwave spectra of multiple isotopic modifications of 2-aminoethanol, for which there is an internal hydrogen bond of the type O-H...N, it has been found that the 0...N distance in the $d_{3} (OD, ND_{2})$ species is shorter than in the normal species by 0.006 {\AA}. Similarly, it has been found that in $d_{5}$ methyldiborane $(CH_{3}B_{2}D_{5})$ the B...B distance is from 0.006 to 0.010 {\AA} shorter than in the normal species. The occurrence of such structural isotope effects precludes simple interpretation of ""substitution structure"" parameters involving the bridge hydrogen. For example, in 2-aminoethanol the ""substitution structure"" parameters $r_{O-H}$ and $\angle COH$, corrected for the small O...N shrinkage which presumably accompanies hydroxy deuteration, are 1.00 {\AA} and $107.4^\circ$, respetively--quite significantly different from the 1.14 {\AA} and $103.7^\circ$ values of the simple substitution structure.en_US
dc.format.extent132358 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleH/D SECONDARY ISOTOPE EFFECTS IN HYDROGEN- AHD HYDRIDE- BRIDGE BONDED COMPOUNDS: 2-AMINOETHANQL AND METHYLDIBORANEen_US
dc.typearticleen_US


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