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dc.creatorCoveieskie, R. A.en_US
dc.creatorParmenter, C. S.en_US
dc.date.accessioned2006-06-15T13:46:55Z
dc.date.available2006-06-15T13:46:55Z
dc.date.issued1976en_US
dc.identifier1976-RE-7en_US
dc.identifier.urihttp://hdl.handle.net/1811/9713
dc.descriptionAuthor Institution: Department of Chemistry, Indiana Universityen_US
dc.description.abstractIn most SVL fluorescence experiments the excitation bandwidth is sufficiently broad to cover essentially the entire rotational contour of the vibronic level excited. As a result the observed contour in emission is generally quite similar to the absorption band contour and represents emission from a rotationally equilibrated vibronic level. By the use of narrow bandwidth excitation $(-- 0.2-0.8 cm^{-1})$, however, a non-Boltzmann rotational distribution can be created in the excited state vibronic level which can be reflected in a change in the shape of the emission band contours. By monitoring the change in band contour as a function of pressure one can get a qualitative picture of the efficiency of rotational equilibration in the excited vibronic level. We wish to report here such experiments performed on the $^{1}{B}_{2u}$ zero-point Level in benzene excited by pumping the $B^{0}_{0}(6^{0}_{1})$ absorption band.en_US
dc.format.extent113611 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleROTATIONAL EQUILIBRATION IN THE EXCITED STATE OF A LARGE POLYATOMIC MOLECULEen_US
dc.typearticleen_US


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