dc.creator Kim, M. S. en_US dc.creator Smalley, R. E. en_US dc.creator Levy, Donald H. en_US dc.date.accessioned 2006-06-15T13:45:57Z dc.date.available 2006-06-15T13:45:57Z dc.date.issued 1976 en_US dc.identifier 1976-RB-10 en_US dc.identifier.uri http://hdl.handle.net/1811/9670 dc.description $^{1}$ J.W.C. Johns, Can. J. Phys. 36, 1738 (1961). $^{2}$ B. S. Snowden, Jr, Ph.D. thesis, Vanderbilt University (1962). $^{3}$ D. K. Russell, M. Kroll, D. A. DOWS, and R. A. Beaudet, Chem. Phys. Lett. 20, 961 (1973). $^{4}$ C. J. Dymek, Ph.D. thesis, The Ohio State University (1974). en_US dc.description Author Institution: The James Franck Institute and The Department of Chemistry, The University of Chicago en_US dc.description.abstract Optical Microwave Double Resonance (OMDR) experiments were performed on the $BO_{2}$ radical in the gas phase. Single mode argon ion laser radiation at 5145 {\AA} and high power microwaves with 2-3 GHz frequency were used producing double resonance signals from the radical. The laser excites the R(7) rotational line of the (110) $^{2}\Sigma^{+}_{g} \leftarrow (010) ^{2}\Sigma^{-}_{\mu}$ vibronic transition from the $^{2}\Pi_{\mu}$ ground state to the $^{2}\Pi_{g}$ excited state. The microwave transitions responsible for the double resonance signals are magnetic dipole transitions among the Zeeman sublevels of the J = 7 1/2 level of the ground state. Two microwave transitions, $(M^{\prime}_{j} = - 4\ 1/2) \leftarrow (M^{\prime\prime}_{j} = - 5 1/2)$ and $(M^{\prime}_{j} = - 3 1/2) \leftarrow (M^{\prime\prime}_{j} = - 4 1/2)$ are identified. Thorough investigation of the Renner effect was carried out. en_US dc.format.extent 104912 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title OPTICAL MICROWAVE DOUBLE RESONANCE OF $BO_{2}$ RADICAL en_US dc.type article en_US
﻿