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dc.creatorBossert, W.en_US
dc.creatorEkkers, J.en_US
dc.creatorBauder, A.en_US
dc.creatorGünthard, Hs. H.en_US
dc.date.accessioned2006-06-15T13:45:22Z
dc.date.available2006-06-15T13:45:22Z
dc.date.issued1976en_US
dc.identifier1976-MS-12en_US
dc.identifier.urihttp://hdl.handle.net/1811/9644
dc.descriptionAuthor Institution: Laboratory for Physical Chemistry, ETH, Universit\""{a}tstren_US
dc.description.abstractAccurate expectation values of the electric dipole operator for molecules with a symmetric internal rotor have been calculated using a semirigid model. Whereas the contributions from dipole components along the principal axes are completely separated for a rigid rotor, they are mixed appreciably for molecules with resolved internal rotation splittings. Combinations with different relative signs of the dipole components lead to different expectation values. This is demonstrated for acetaldehyde $(CH_{3}CHO)$ through the effect on the Stark splittings. Several transitions including excited torsional states have been analyzed and the relative signs of the dipole components have been determined.en_US
dc.format.extent98268 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleSTARK EFFECT IN ACETALDEHYDE: RELATIVE SIGN OF DIPOLE COMPONENTSen_US
dc.typearticleen_US


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