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dc.creatorPenn, R. E.en_US
dc.creatorBuxton, L. W.en_US
dc.creatorBirkenmeier, J. A.en_US
dc.date.accessioned2006-06-15T13:39:34Z
dc.date.available2006-06-15T13:39:34Z
dc.date.issued1975en_US
dc.identifier1975-RG-16en_US
dc.identifier.urihttp://hdl.handle.net/1811/9385
dc.description$^{1}$ R. E. Penn and L. H. Buxton, J. Mol. Spectrosc. (in press).en_US
dc.description$^{2}$ R. E. Penn and R. F. Curl, JR., J. Chem. Phys. 55, 651 (1971).""en_US
dc.descriptionThis work has had the combined support of a Smarter Research Fellowship from of University of Missouri and a grant from Research Corporation.en_US
dc.descriptionAuthor Institution: Department of Chemistry, University of Missourien_US
dc.description.abstractFrom their microwave spectra, $2-methylaminoethanol^{1}$ and 2-dimethylaminoethanol have been found to have gauche OCCN configurations and $O-H\cdots N$ type intramolecular hydrogen bonds. The conformational equilibrium between two rotamers of the former, one with a trans CCMC configuration (``GT”) and one with a gauche CCNC configuration (“GG”) favors the “GT” form, due to a ground state $\Delta$E of 0.46 kcal/mole. The configurations about the central C-N bonds. compared to that of $2-aminoethanol,^{2}$ reflect the combined influence of the hydrogen bond, the $C-N$ internal rotation barrier and a 1,4 nonbonded hydrogen repulsion. The differences between the observed and predicted dipole components suggest a 0.5 D polarization of the nitrogen nonbonding electrons by the hydroxy proton. The hydroxy $d_{1}$ spectrum of 2-dimethylaminoethanol is consistent with either an extraordinarily Long O-H bond (1.235\AA) or an approximate 0.01\AA shrinkage in the $O\cdots N$ distance accompanying deuteration.en_US
dc.format.extent159583 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleHYDROGEN BONDING IN 2-METHYL- AND 2-DIMETHYLAMINOETHANOL BY MICROWAVE SPECTROSCOPYen_US
dc.typearticleen_US


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