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dc.creatorAult, Gary M.en_US
dc.creatorGraybeal, Jack D.en_US
dc.date.accessioned2006-06-15T13:39:31Z
dc.date.available2006-06-15T13:39:31Z
dc.date.issued1975en_US
dc.identifier1975-RG-14en_US
dc.identifier.urihttp://hdl.handle.net/1811/9383
dc.descriptionAuthor Institution: Department of Chemistry, Virginia Polytechnic Institute and State Universityen_US
dc.description.abstractThe microwave spectrum of monoiodoacetonitrile, $CH_{2}ICN$, has been investigated in the P- and R-band regions using a conventional Stark-modulated spectrometer. Twelve transitions, with their attendant hyper-fine components, have been assigned. Second order quadrupole effects are prominent in the spectrum and the analysis gave $\chi_{aa} = -1276$ MHz, $\chi_{bb} 233$ MHz, $\chi_{ab} = 1370 s$ MHz, $\chi_{ZZ} = -2086$ MHz and $\theta_{az} = 30.6^{\circ}$. A rigid rotor fit of the transitions gave moments of $A = 20 037.32 \pm 3.00$ MHz, $B = 1747.95 \pm 0.21$ MHZ and $C = 1622.87 \pm 0.23$ MHz. Using the $CH_{2}CN$ skeletal structure of monobromoacetonitrile, values of $r_{CI} = 2.145$ {\AA} and $\angle CCI = 111.47^{\circ}$ are consistent with the observed moments.en_US
dc.format.extent104312 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleMICROWAVE SPECTRUM AND QUADRUPOLE COUPLING IN MONOIODOACETONITRILEen_US
dc.typearticleen_US


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