ACCURATE THEORETICAL OSCILLATOR STRENGTHS FOR DIATOMIC MOLECULES, CH AND OH
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Publisher:Ohio State University
Extended configuration interaction wavefunctions have been used to calculate dipole transition moment curves for the valence states of CH and OH. These curves have been used to calculate radiative lifetimes and oscillator strengths as functions of vibrational and rotational quantum numbers. The calculated absolute transition probabilities agree with experimental results to within $\sim$ 150\%. Considerably better agreement was found for relative transition probabilities.
Author Institution: IBM Research Laboratory