AN ANALYSIS OF THE $^{1}B_{2}$ (2350 {\AA}) SYSTFM OF $SO_{2}$
Publisher:
Ohio State UniversityAbstract:
The vibrational structure of the $^{1}B_{2}$ system has been interpreted in terms of a double minimum potential in the antisymmetric stretch vibration and strong anharmonic coupling between the symmetric and antisymmetric stretches. The results of recent rotational analyses and $S^{18}O_{2}$ vibrational isotope shifts have also been incorporated. The present analysis gives a barrier height considerably lower than that derived previously by Coon and his co-$workers,^{1}$ although their assignments have, in general, been confirmed.
Description:
$^{1}$ J. B. Coon and F. A. Cesani, Bull. Am. Phys. Soc. 10, 157 (1965).""
Author Institution: Department of Chemistry, University of Western Ontario
Author Institution: Department of Chemistry, University of Western Ontario
Type:
articleOther Identifiers:
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