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dc.creatorVan Zee, R. J.en_US
dc.creatorKhan, Ahsan U.en_US
dc.date.accessioned2006-06-15T13:36:23Z
dc.date.available2006-06-15T13:36:23Z
dc.date.issued1975en_US
dc.identifier1975-FD-06en_US
dc.identifier.urihttp://hdl.handle.net/1811/9243
dc.description$^{1}$R. J. Van Zee and A. U. Khan, J. Amer. Chem. Soc. 96, 6805 (1974).""en_US
dc.descriptionAuthor Institution: Departments of Chemistry and Biophysics,, Michigan State Universityen_US
dc.description.abstractRecently the emitting species in phosphorus chemiluminescence under ambient conditions have been identified as HPO, P0 $\gamma$-system and (PO)$_{2}^{*}$ $excimer.^{1}$ We have verified that the major visible emitting species is (PO)$_{2}^{*}$ excimer by observing the thermal dissociation of the excimer and the consequent appearance of the (0,0) transition of the PO $\beta$-system in the spectra. Further confirmation was given by diluting the system with a buffer gas affecting the equilibrium $(P0)_{2}^{*} \leftrightarrow PO(^{4}\Pi) + PO(X^{2}\Pi) \leftrightarrow PO(X^{2}\Pi) + PO(B^{2}\Sigma^{+}$) to enhance the PO $\beta$-system emission. Drying the reactants beforehand decreases the HPO emission without a major effect on the continuum emission, which eliminates the possibility that the continuum could arise from a species containing hydrogen.en_US
dc.format.extent116359 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleTRANSIENT EMITTING SPECIES IN PHOSPHORUS CHEMILUMINESCENCEen_US
dc.typearticleen_US


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