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dc.creatorBates, John B.en_US
dc.creatorStidham, Howard D.en_US
dc.date.accessioned2006-06-15T13:36:16Z
dc.date.available2006-06-15T13:36:16Z
dc.date.issued1975en_US
dc.identifier1975-FC-10en_US
dc.identifier.urihttp://hdl.handle.net/1811/9237
dc.descriptionThis research was sponsored by Energy Research and Development Administration under contract with Union Carbide Corporation.en_US
dc.descriptionAuthor Institution: Solid State Division, Oak Ridge National Laboratory; Department of Chemistry, University of Massachusettsen_US
dc.description.abstractResonance Raman scattering and electronic absorption spectroscopy have been used to study radiation effects in single crystals of $NaClO_{3}$ and $KClO_{3}$. Interaction of ionizing radiation with $CL0_{3}^{-}$ ions produces species such as $O^{-}_{3}$, $O^{-}_{2}$, $C1O^{-}$, and $C1O^{-}_{2}$ ions which are trapped at various sites in the crystal lattice. By irradiating crystals at $77^{\circ} K$, the unstable precursors of these species can also be studied. The electronic and resonance Raman spectra of some unstable intermediate and final products of the radiolytic decomposition of $NaCLO_{3}$ and $KCLO_{3}$ are reported. The results are used to sketch ground and excited electronic state properties of some of the ions that occur along the decomposition pathways in these crystals.en_US
dc.format.extent133438 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleRESONANCE RAMAN AND ELECTRONIC ABSORPTION SPECTROSCOFY OF ELECTRON AND $\gamma$-RAY IRRADIATED SINGLE CRYSTALS OF ALKALI-METAL CHLORATESen_US
dc.typearticleen_US


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