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dc.creatorRitzhaupt, G.en_US
dc.creatorDevlin, J. Paulen_US
dc.date.accessioned2006-06-15T13:35:57Z
dc.date.available2006-06-15T13:35:57Z
dc.date.issued1975en_US
dc.identifier1975-FB-06en_US
dc.identifier.urihttp://hdl.handle.net/1811/9222
dc.description$^{1}$N. Smyrl and J.P. Devlin, J. Chem. Phys. 60, 2540 (1974). $^{2}$Ibid., 61, 1596 (1974).""en_US
dc.descriptionAuthor Institution: Department of Chemistry, Oklahoma State Universityen_US
dc.description.abstractThe vibrational spectra of simple contact ion pairs, such as $M^{+}NO_{3}^{-}, M^{+}ClO_{3}^{-}$ and $M^{+}ClO_{4}^{-}$, isolated in argon matrices have been determined in previous $studies.^{1}$ More recently it has been shown that the cation distortion of the anion, as indicated by the magnitude of the splittinge £or the degenerate modes is sharply decreased in glassy water and glassy ammonia $matrices.^{2}$ This phenomenon is attributed to the electron donor action associated with the partial solvation of the metal cations by the matrix molecules. In this paper the step-wise solvation of the cations in the contact ion pairs will be displayed in the variation in magnitude of the splitting of the degenerate modes for the complete range of argon-associating matrix compositions. Certain published liquid solution spectra will be considered in view of the new contact ion pair results.en_US
dc.format.extent133619 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleSTRUCTURES OF SALT SOLUTIONS FROM MATRIX ISOLATION SPECTRAen_US
dc.typearticleen_US


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