ON THE ROTATION OF FREE AND) COMPLEXED $NH_{3}$ IN SOLID NITROGEN AT TEMPERATURES BELOW $15^{\circ} K$

dc.creator	Fredin, Leif	en_US
dc.creator	Nelander, B.	en_US
dc.creator	Ribbegård, Göran	en_US
dc.date.accessioned	2006-06-15T13:35:54Z
dc.date.available	2006-06-15T13:35:54Z
dc.date.issued	1975	en_US
dc.identifier	1975-FB-04	en_US
dc.identifier.uri	http://hdl.handle.net/1811/9220
dc.description	Author Institution: Thermochemistry Laboratory, Chemical Center, Lund University; National Research Council of Canada, Ottawa, Ontario, Canada, KLA OR6.	en_US
dc.description.abstract	The infrared spectra of ammonia and the ammonia-chlorine (1:1) complex have been studied in solid nitrogen at temperatures between 6 and $20^{\circ} K$. The E symmetric vibrations show a characteristic fine structure at low temperatures, both for free and complexed ammonia. The fine structure components broaden reversibly at higher temperatures. The low temperature spectrum can be interpreted as evidence for restricted rotation of ammonia around its $c_{3}$ axis, with a sixfold potential barrier.	en_US
dc.format.extent	99232 bytes
dc.format.mimetype	image/jpeg
dc.language.iso	English	en_US
dc.publisher	Ohio State University	en_US
dc.title	ON THE ROTATION OF FREE AND) COMPLEXED $NH_{3}$ IN SOLID NITROGEN AT TEMPERATURES BELOW $15^{\circ} K$	en_US
dc.type	article	en_US