DIPOLE MOMENT OF IODINE MONOCHLORINE
Publisher:
Ohio State UniversityAbstract:
The $J = 2 \leftarrow 1$ microwave spectra of $I^{35}Cl$ and $I^{37}Cl$ were measured for the $v = 0$ and $v = 1$ vibrational levels. The dipole moment $a(v = 0) = 1.24(2)D$ was determined by stark effect measurements. Use of second order perturbation theory to solve the Stark effect yields an incorrect result, requiring diagonalization of a truncated Stark matrix. Improved values of the rotational and quadrupole coupling constants were obtained, and the iodine nuclear spin-rotation constant was determined.
Description:
Author Institution: Department of Chemistry, Harvard University Cambridge
Type:
articleOther Identifiers:
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