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dc.creatorBates, John K.en_US
dc.creatorDunn, T. M.en_US
dc.date.accessioned2006-06-15T13:33:47Z
dc.date.available2006-06-15T13:33:47Z
dc.date.issued1972en_US
dc.identifier1972-Sigma-08en_US
dc.identifier.urihttp://hdl.handle.net/1811/9120
dc.descriptionAuthor Institution: Department of Chemistry, University of Michiganen_US
dc.description.abstractThe electronic spectrum of ZrN has been observed and one band system fully analyzed for both $ZrN^{14}$ and $ZrN^{15}$. The transition is $^{2}\Pi_{r} \rightarrow ^{2}\Sigma$ with the two subband heads at 5647.59 and 5835.08. Extensive perturbations have been observed in both these spectra and these will also be discussed. The rotational constants for the ground and excited states of the $Zr^{90}N^{14}$ species are approximately 0.4832 and 0.4798 respectively. The spin orbit coupling constant of the $^{2}\Pi$ is approximately $567 cm^{-1}$. Some other transition metal nitrides have also been observed in emission and their systems will be briefly discussed.en_US
dc.format.extent85675 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleOPTICAL SPECTRA OF TRANSITION METAL NITRIDES. ZrNen_US
dc.typearticleen_US


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