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dc.creatorMcAdams, Mary Janeen_US
dc.creatorRussell, B. R.
dc.date.accessioned2006-06-15T13:32:33Z
dc.date.available2006-06-15T13:32:33Z
dc.date.issued1972en_US
dc.identifier1972-M-2en_US
dc.identifier.urihttp://hdl.handle.net/1811/9062
dc.descriptionThis work was supported by the Robert A. Welch Foundationen_US
dc.descriptionAuthor Institution: Department of Chemistry, North Texas State Universityen_US
dc.description.abstractThe electronic spectra of the fluorine and chlorine substituted trivalent phosphorus have been measured in the vapor phase between 2000 and ca. $1200^{\circ}$ \AA. Systematic replacement of fluorine by chlorine in $PF_{3}$ $(PF_{3}$, $PF_{2} $Cl, $PFCl_{2}$ and $PCl_{3}$) corresponds to a noticeable increase in the number of absorption maxima. The spectral trends are considered in terms of the electron-withdrawing properties of the respective halogens. Specific consideration of the chlorine and phosphorus non-bonding electrons and their contributions to the spectral absorptions are made. The assignments will be discussed utilizing the reslts of a CNDO molecular orbital calculation.en_US
dc.format.extent103239 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleSPECTRA OF FLUORINE-CHLORINE SUSTITUTED TRIVALENT PHOSPHORUSen_US
dc.typearticleen_US


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