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dc.creatorChi, F. K.en_US
dc.creatorLeroi, G. E.en_US
dc.date.accessioned2006-06-15T13:31:23Z
dc.date.available2006-06-15T13:31:23Z
dc.date.issued1972en_US
dc.identifier1972-H-10en_US
dc.identifier.urihttp://hdl.handle.net/1811/9008
dc.descriptionAuthor Institution: Department of Chemistry, Michigan State Universityen_US
dc.description.abstractVibrational spectra have been obtained for diazopropyne, $H-C\equiv C-\stackrel{H}{C}=N=N$, and its deuterated analogs in the gaseous and solid states, and in matrix isolation. A valence force field vibrational analysis has been performed (assuming $C_{S}$ symmetry) using initial parameters from related molecules, refined to fit the infrared and Raman spectra of the isotopic species. Photolysis of matrix isolated diazopropyne gives rise to several new spectral features, some attributable to the propargylene free radical. The existence of triplet $H-\dot{C}=C=\dot{C}-H$ in the matrix is confirmed by esr measurements. The vibrational analysis of : $C_{3}H_{2}$, : $C_{3}HD$, and : $C_{3}D_{2}$ has been carried out on the basis of $D_{\infty h}$ synmetry.en_US
dc.format.extent95355 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleVIBRATIONAL SPECTRA OF DIAZOPROPYNE $(C_{3}H_{2}N_{2})$ AND ITS MATRIX-ISOLATED PHOTOLYSIS PRODUCTSen_US
dc.typearticleen_US


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