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dc.creatorPickett, H. M.en_US
dc.creatorWilson, E. Bright, Jr.en_US
dc.date.accessioned2006-06-15T13:30:35Z
dc.date.available2006-06-15T13:30:35Z
dc.date.issued1972en_US
dc.identifier1972-E-5en_US
dc.identifier.urihttp://hdl.handle.net/1811/8971
dc.descriptionAuthor Institution: Department of Chemistry, Harvard Universityen_US
dc.description.abstractThe microwave spectrum of amino acetonitrile, in the region 26.5-40 GHz, is dominated by two sets of prolate a-type R branch lines and a b-type Q branch series. Only one rotameric species is found and no exceptionally low-energy vibrational satellites are seen. When $D_{2}O$ is present in the waveguide, the $ND_{2}$ species and one NHD species are observed. The changes in rotational constant upon deuteration suggest that the most stable species is the form with a plane of symmetry in which the amino protons are directed toward the cyano group. This evidence and the lack of low vibrational states and other rotamers suggest that the molecule is locked in the stable form by dipole-dipole forces.en_US
dc.format.extent96723 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleTHE MICROWAVE SPECTRUM OF AMINO ACETONITRILEen_US
dc.typearticleen_US


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