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dc.creatorBair, E. J.en_US
dc.creatorRamsay, D. A.en_US
dc.date.accessioned2006-06-15T13:28:24Z
dc.date.available2006-06-15T13:28:24Z
dc.date.issued1971en_US
dc.identifier1971-W-2en_US
dc.identifier.urihttp://hdl.handle.net/1811/8872
dc.description$^{1}$Visiting Scientist from the Department of Chemistry, Indiana University, Bloomington, Indiana 47401, U. S. A.""en_US
dc.descriptionAuthor Institution: Division of Physics, National Research Council of Canadaen_US
dc.description.abstractThe magnetic rotation spectrum of acrolein has been studied using an apparatus 1 m long and field strengths up to 5000 G. The effective path length was increased by a factor of 8 by the use of external multiple reflection mirrors. Five bands have been found at 4040, 4122, 4178, 4220 and 4322 \AA. The first four bands are assigned to the $^{3}$^{\prime\prime} --- $^{1}A$^{\prime} ($\pi^{*}$ - n) system of trans acrolein with the 0-0 band at 4122 A. The fifth band at 4322 \AA is assigned as the 0-0 band of the $^{3}A$^{\prime\prime} --- $^{1}A$^{\prime} ($\pi^{*}$ --- n) transition of the cis (or gauche) isomer. An energy level diagram showing the relative energies of the cis (or gauche) and trans isomers in the ground $^{1}A$^{\prime} and excited $^{1}A$^{\prime\prime} and $^{3}A$^{\prime\prime} ($\pi^{*}$ --- n) states will be shown.en_US
dc.format.extent88988 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleTHE MAGNETIC ROTATION SPECTRUM OF ACROLEIN: CIS AND TRANS ISOMERSen_US
dc.typearticleen_US


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