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dc.creatorBartoli, F. J.en_US
dc.creatorLitovitz, T. A.en_US
dc.date.accessioned2006-06-15T13:27:39Z
dc.date.available2006-06-15T13:27:39Z
dc.date.issued1971en_US
dc.identifier1971-Sigma-22en_US
dc.identifier.urihttp://hdl.handle.net/1811/8836
dc.description$^{*}$This research was supported by the National Science Foundation.en_US
dc.descriptionAuthor Institution: Optical Sciences Division, U. S. Naval Research Laboratory; Department of Physics, The Catholic University of Americaen_US
dc.description.abstractA systematic investigation of orientational broadening of Raman vibrational lines is undertaken and measurements of lineshapes are for nineteen liquids. The problem of separating orientational broadening from the intrinsic vibrational lineshape is discussed in detail and a method of analysis is presented. The advantages and limitations of this method are considered and compared to an earlier method proposed by Rakov. The intrinsic width is determined for each line studied and removed from the spectrum to give the orientational broadening. It is noted that the intrinsic lineshape, measured from polarized Raman spectra, may be used to correct infrared vibrational spectra which suffer from the same problems. It is shown that neglect of intrinsic width can lead to significant errors in the interpretation of infrared data.en_US
dc.format.extent104950 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleANALYSIS OF ORIENTATIONAL BROADENING OF RAMAN $LINESHAPES^{*}$en_US
dc.typearticleen_US


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