Show simple item record

dc.creatorKoyanagi, Motohikoen_US
dc.creatorGoodman, Lionelen_US
dc.description$^{*}$Supported by National Science Foundation Grant GP 6301X.en_US
dc.descriptionAuthor Institution: School of Chemistry, Rutgers Universityen_US
dc.description.abstractThe fine vibronic structure of benzaldehyde phosphorescence was observed in close packing matrices at 4.2 K and analyzed almost completely. The lifetimes were also measured at 4.2 K and 1.68 K. The results are: (1) the $^{3}U-^{1}S_{o}$ transition obtains a large part of its probability vibronically from the $^{1}U-S_{o}$ transition via a^{\prime\prime} nontotally symmetric vibrations; (2) the coupling scheme is discussed. Deuteration effects confirm the large vibronic contribution to the probability.en_US
dc.format.extent72690 bytes
dc.publisherOhio State Universityen_US
dc.titleVIBRONIC INTERACTIONS IN THE $^{3} U$ ($n\pi^{*}$) $\leftarrow$ $S_{o}$ PHOSPHORESCENCE OF $BENZALDEHYDE^{*}$en_US

Files in this item


Items in Knowledge Bank are protected by copyright, with all rights reserved, unless otherwise indicated.

This item appears in the following Collection(s)

Show simple item record