INFRARED MATRIX ISOLATION STUDIES OF CICN AND BrCN: FERMI RESONANCE AND DIMER STRUCTURE

dc.creator	Freedman, Teresa L.	en_US
dc.creator	Nixon, Eugene R.	en_US
dc.date.accessioned	2006-06-15T13:25:02Z
dc.date.available	2006-06-15T13:25:02Z
dc.date.issued	1971	en_US
dc.identifier	1971-I-7	en_US
dc.identifier.uri	http://hdl.handle.net/1811/8712
dc.description	Author Institution: Department of Chemistry and Laboratory for Research on the Structure of Matter, University of Pennsylvania	en_US
dc.description.abstract	The infrared spectra of ClCN and BrCN in argon and krypton matrices at $20^{\circ} K$ have been investigated. There is good evidence that for the monomeric species in the matrices, the bending mode is split by the matrix environment and that the first overtones of these two bending components form a Fermi resonant triad with the $v_{1}$ fundamental. The frequencies and relative intensities of the three bands have been used to calculate unperturbed frequencies and Fermi coupling constants. The absorption bands due to dimeric species are consistent with a linear configuration for the dimer.	en_US
dc.format.extent	83270 bytes
dc.format.mimetype	image/jpeg
dc.language.iso	English	en_US
dc.publisher	Ohio State University	en_US
dc.title	INFRARED MATRIX ISOLATION STUDIES OF CICN AND BrCN: FERMI RESONANCE AND DIMER STRUCTURE	en_US
dc.type	article	en_US