dc.creator Freedman, Teresa L. en_US dc.creator Nixon, Eugene R. en_US dc.date.accessioned 2006-06-15T13:25:02Z dc.date.available 2006-06-15T13:25:02Z dc.date.issued 1971 en_US dc.identifier 1971-I-7 en_US dc.identifier.uri http://hdl.handle.net/1811/8712 dc.description Author Institution: Department of Chemistry and Laboratory for Research on the Structure of Matter, University of Pennsylvania en_US dc.description.abstract The infrared spectra of ClCN and BrCN in argon and krypton matrices at $20^{\circ} K$ have been investigated. There is good evidence that for the monomeric species in the matrices, the bending mode is split by the matrix environment and that the first overtones of these two bending components form a Fermi resonant triad with the $v_{1}$ fundamental. The frequencies and relative intensities of the three bands have been used to calculate unperturbed frequencies and Fermi coupling constants. The absorption bands due to dimeric species are consistent with a linear configuration for the dimer. en_US dc.format.extent 83270 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title INFRARED MATRIX ISOLATION STUDIES OF CICN AND BrCN: FERMI RESONANCE AND DIMER STRUCTURE en_US dc.type article en_US
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