MICROWAVE SPECTRUM OF METHOXYDIFLUOROPHOSPHINE
Publisher:
Ohio State UniversityAbstract:
Rotational transitions with large splittings attributed to internal rotation of the Methyl group have been assigned in the microwave spectra of $CH_{3}OPF_{2}$, $^{13}CH_{3}OPF_{2}$, and $CD_{3}OPF_{2}$. The effective rotational constants for the A levels of the parent species are A = 5988.97 MHz, B = 3641.80 MHz, and C = 3127.90 MHz. The barrier to internal rotation of the methyl group is $V_{3} = 433 \pm 20$ cal/mole. The structure of the molecule and the analysis of the internal rotation splittings will be discussed.
Description:
This research was supported, in part, by a grant from the National Science Foundation.""
Author Institution: Department of Chemistry, Michigan State University
Author Institution: Department of Chemistry, Michigan State University
Type:
articleOther Identifiers:
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