THE MICROWAVE SPECTRUM OF CYCLOPROPYL METHYL ETHER
Creators:Penn, R. E.
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Publisher:Ohio State University
The microwave spectrum of cyclopropyl methyl ether has been found to be dominated by “b” - and “c”-type dipole transitions of a gauche rotamer. From quantitative Stark effect measurements the dipole moment components have been determined. The development of the asymmetry/internal rotation splitting and intensity pattern has been followed from the psuedo rigid rotor low K states to the non rigid rotor high K states, and the methyl barrier to internal rotation has been determined.
Author Institution: Department of Chemistry, The University of Texas at Austin
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