Show simple item record

dc.creatorBottger, Gary L.en_US
dc.date.accessioned2006-06-15T13:23:44Z
dc.date.available2006-06-15T13:23:44Z
dc.date.issued1971en_US
dc.identifier1971-C-9en_US
dc.identifier.urihttp://hdl.handle.net/1811/8651
dc.descriptionAuthor Institution: Eastman Kodak Research Laboratoriesen_US
dc.description.abstractThe Raman and infrared spectra of alkali salts of octahedral iridium hexahalide complexes and osmium hexahalide complexes have been measured at room temperature. Lattice vibrations and stretching and bending frequencies of the metal-halogen bonds were observed and interpreted. Force constant calculations were used to obtain values for unobservable fundamental modes, and to compare bond strengths among various 5d hexahalometalate ions. Certain dramatic differences in the relative intensities of $v_{1}$ and $v_{2}$ in $IrCl_{n}^{2-}$, $IrBr_{6}^{2-}$, $IrI_{6}^{-2}$, $OsCl_{6}^{2-}$, and $OsBr_{6}^{2-}$ indicate that the supposed occurrence of dynamic Jahn-Teller effects may in some cases be quenched by spin-orbit interaction and/or charge transfer.en_US
dc.format.extent86264 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleVIBRATIONAL SPECTRA OF THE HEXAHALOMETALATE COMPLEXES OF THE PLATINUM METALSen_US
dc.typearticleen_US


Files in this item

Thumbnail

Items in Knowledge Bank are protected by copyright, with all rights reserved, unless otherwise indicated.

This item appears in the following Collection(s)

Show simple item record