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dc.creatorGillies, C. W.en_US
dc.creatorKuczkowski, R. L.en_US
dc.date.accessioned2006-06-15T13:23:23Z
dc.date.available2006-06-15T13:23:23Z
dc.date.issued1971en_US
dc.identifier1971-B-5en_US
dc.identifier.urihttp://hdl.handle.net/1811/8634
dc.description$^{1}O_{1}$ denotes a peroxide oxygen while $O_{e}$ denotes an ether oxygen in the ring.en_US
dc.descriptionAuthor Institution: Department of Chemistry, University of Michiganen_US
dc.description.abstractThe structure of 1,2,4-trioxacyclopentane $OCH_{2}OOCH_{2}$ was determined from the microwave spectra of four isotopic species. No significant deviation from the rigid rotor approximation was observed and the conformation has $C_{2}$ symmetry (half chair conformation). The following are some of the more important structural $parameters:^{1}$ bond distances (A), $r(O{p}O_{p}) = 1.471 (0.009)$, $r(CO_{p}) = 1.397 (0.006)$, $r(CO_{p}) = 1.433 (0.009)$, $r (CH) = 1.094 (0.005)$; bond angles. $<COC = 103.1 (0.6), <COO = 99.20 (0.22), <OCO = 106.3 (0.4), <HCH = 113.1 (0.6)$; torsional angle, $\Phi(O_{p}O_{p}) = 49.97 (0.36)$.en_US
dc.format.extent91616 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleTHE MICROWAVE SPECTRUM AND MOLECULAR STRUCTURE OF 1,2,4-TRIOXACYCLOPENTANEen_US
dc.typearticleen_US


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