THE VIBRATIONAL SPECTRA AND STRUCTURE OF IODOACETIC ACID
Publisher:
Ohio State UniversityAbstract:
The vibrational spectra of iodoacetic acid have been studied in the liquid and solid states. Spectra of sodium iodoacetate and iodoacetic acid-$d_{1}$ have been determined to aid in the assignment of the fundamental vibrations of the parent acid. In contrast to chloroacetic acid, the most stable polymorph of crystalline iodoacetic acid possesses the hydrogen bonded dimer structure. This structure appears to be maintained in the liquid phase. Only one rotational isomer is detectable in the liquid state.
Description:
This work was supported in part by the U.S. Air Force under Contracts F33615--67--C--1363 and F33615--70--C--1021.
Author Institution: Department of Chemistry, Miami University; Sherwin-Williams Company, Research Center
Author Institution: Department of Chemistry, Miami University; Sherwin-Williams Company, Research Center
Type:
articleOther Identifiers:
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