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dc.creatorPacansky, Jacoben_US
dc.creatorCalder, V.en_US
dc.date.accessioned2006-06-15T13:19:42Z
dc.date.available2006-06-15T13:19:42Z
dc.date.issued1970en_US
dc.identifier1970-J-9en_US
dc.identifier.urihttp://hdl.handle.net/1811/8455
dc.descriptionAuthor Institution: Institute for Atomic Research and Department of Chemistry, Iowa State Universityen_US
dc.description.abstractAlthough the vibration-rotation spectra of $H_{2} S$ and $D_{2} S$ have been the object of extensive study, the assignment of the $v_{3}$ mode has never been observed in the gas phase. The matrix spectra reported here are analyzed in terms of the uncoupled oscillator approximation. This approach offers several advantages: 1) A separate eigenvalue equation can be written for each vibrational frequency. 2) Simple, geometry-independent, expressions relate the force constants to the isotopic shifts. 3) The frequency shift caused by the matrix cancels from the force constant calculation. 4) The neglect of anharmonicity is easy to assess.en_US
dc.format.extent73360 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleTHE MATRIX ISOLATION SPECTRA OF $H_{2} S$ AND $D_{2}S$: AN EXAMPLE OF THE APPLICATION OF THE UNCOUPLED OSCILLATOR APPROXIMATIONen_US
dc.typearticleen_US


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