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dc.creatorSpiker, Robert C.en_US
dc.creatorAndrews, Lesteren_US
dc.date.accessioned2006-06-15T13:19:39Z
dc.date.available2006-06-15T13:19:39Z
dc.date.issued1970en_US
dc.identifier1970-J-6en_US
dc.identifier.urihttp://hdl.handle.net/1811/8452
dc.descriptionAuthor Institution: Department of Chemistry, University of Virginiaen_US
dc.description.abstractLithium oxides of the form $Li_{2} O$ and LiO have been produced for infrared study by the reaction of lithium atoms and nitrous oxide molecules at high dilution in nitrogen matrices. Analogous experiments using argon matrices produced no $Li_{2}O$ or LiO species. Assignments made to LiO and the antisymmetric Li-O stretch of $Li_{2}O$ are confirmed by isotopic substitutions of lithium and oxygen atoms, concentration studies, and comparison to earlier evaporative $Li_{2} O$ work. Force constants calculated using the observed isotopic frequencies agree within 0.4% for four isotopic combinations of $Li_{2}O$ and LiO. Normal coordinate calculations agree with earlier conclusions that $Li_{2}O$ is a linear molecule.en_US
dc.format.extent83240 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleINFRARED SPECTRA OF $Li_{2} O$ AND LiO PRODUCED BY MATRIX REACTIONSen_US
dc.typearticleen_US


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