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dc.creatorBrown, Farrell B.en_US
dc.creatorFletcher, W. H.en_US
dc.date.accessioned2006-06-15T13:13:24Z
dc.date.available2006-06-15T13:13:24Z
dc.date.issued1963en_US
dc.identifier1963-P-9en_US
dc.identifier.urihttp://hdl.handle.net/1811/8298
dc.description$^{*}$This work was supported mainly by a grant from the National Science Foundation and in part by the Robert A. Welch Foundation, Houston, Texas.en_US
dc.descriptionAuthor Institution: Department of Chemistry, A. and M. College of Texas; Department of Chemistry, University of Tennesseeen_US
dc.description.abstract“The infrared and Raman Spectra of $H_{2}NCN$ and $D_{2}NCN$ have been examined in the region of $2.5\mu$ to $35\mu$. Polarization data imply a planar configuration, but the experimental data for the region beyond 12 $\mu$ are inconsistent with this. The observed product rule ration for the symmetric N--H stretch, $NH_{2}$ deformation, N--C stretch and the $C\equiv N$ stretches are also inconsistent with a planar molecule. The observations do fit a non-planar molecule with an invertion barrier described by a Manning potential. Properties of the continued fraction arising from the Manning potential and their effect upon the calculated transitions are discussed. From the calculated and observed inversion spectrum, the barrier height, and equilibrium position are found to be $660 cm^{-1}$ and 0.17 {\AA} respectively. Practivally every distinct feature of the infrared and Raman spectra of the liquid state for both isotopic species may be given a satisfactory assignment with this model.”en_US
dc.format.extent114521 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleTHE VIBRATIONAL SPECTRUM, STRUCTURE, AND INVERSION MODE OF CYANAMIDEen_US
dc.typearticleen_US


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