dc.creator Brown, Farrell B. en_US dc.creator Fletcher, W. H. en_US dc.date.accessioned 2006-06-15T13:13:24Z dc.date.available 2006-06-15T13:13:24Z dc.date.issued 1963 en_US dc.identifier 1963-P-9 en_US dc.identifier.uri http://hdl.handle.net/1811/8298 dc.description $^{*}$This work was supported mainly by a grant from the National Science Foundation and in part by the Robert A. Welch Foundation, Houston, Texas. en_US dc.description Author Institution: Department of Chemistry, A. and M. College of Texas; Department of Chemistry, University of Tennessee en_US dc.description.abstract “The infrared and Raman Spectra of $H_{2}NCN$ and $D_{2}NCN$ have been examined in the region of $2.5\mu$ to $35\mu$. Polarization data imply a planar configuration, but the experimental data for the region beyond 12 $\mu$ are inconsistent with this. The observed product rule ration for the symmetric N--H stretch, $NH_{2}$ deformation, N--C stretch and the $C\equiv N$ stretches are also inconsistent with a planar molecule. The observations do fit a non-planar molecule with an invertion barrier described by a Manning potential. Properties of the continued fraction arising from the Manning potential and their effect upon the calculated transitions are discussed. From the calculated and observed inversion spectrum, the barrier height, and equilibrium position are found to be $660 cm^{-1}$ and 0.17 {\AA} respectively. Practivally every distinct feature of the infrared and Raman spectra of the liquid state for both isotopic species may be given a satisfactory assignment with this model.” en_US dc.format.extent 114521 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title THE VIBRATIONAL SPECTRUM, STRUCTURE, AND INVERSION MODE OF CYANAMIDE en_US dc.type article en_US
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