Show simple item record

dc.creatorYeranos, Walter A.en_US
dc.creatorBelford, R. Linnen_US
dc.date.accessioned2006-06-15T13:12:12Z
dc.date.available2006-06-15T13:12:12Z
dc.date.issued1963en_US
dc.identifier1963-H-1en_US
dc.identifier.urihttp://hdl.handle.net/1811/8239
dc.description$^{*}$Supported by NSF, University of Illinois Research Board, and an Alfred P. Sloan Research Fellowship.en_US
dc.descriptionAuthor Institution: Noyes, Chemical Laboratory, University of Illinoisen_US
dc.description.abstract“Using the probable symmetry of several cupric chelates dissolved in $CHCl_{3}$ or $C_{3}H_{3}N$, one can infer some rational trends in the electric dipole intensity of the copper d-d absorption bands. It is postulated that the centric molecules show only weak $(\epsilon < 100)$ vibrationlly induced transitions; acentric molecules should have higher transition moments. The intensity in each case, should increase when the compound is monopyridinated. Spectra, of solutions of two series of chelates chosen for their symmetry variations are in reasonable accord with the predictions. Judiciously used, intensity of visible absorption bands of a new cupric species can provide useful about its geometry, more frequent use of this evidence is recommended.”en_US
dc.format.extent82333 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleEFFECT OF SYMMETRY ON VISIBLE-BAND INTENSITIES OF CUPRIC $CHELATES^{*}$en_US
dc.typearticleen_US


Files in this item

Thumbnail

Items in Knowledge Bank are protected by copyright, with all rights reserved, unless otherwise indicated.

This item appears in the following Collection(s)

Show simple item record