dc.creator Hodgeson, Jimmie A. en_US dc.creator Curl, R. F., Jr. en_US dc.date.accessioned 2006-06-15T13:11:26Z dc.date.available 2006-06-15T13:11:26Z dc.date.issued 1963 en_US dc.identifier 1963-C-9 en_US dc.identifier.uri http://hdl.handle.net/1811/8202 dc.description $^{*}$This work, was supported by a grant from the Robert A. Welch Foundation. $^{\dag}$Alfred P. Sloan Foundation Fellow. $^{1}$Bird, Baird, Rosenthal, et. al., (to be published). en_US dc.description Author Institution: Department of Chemistry, Rice University en_US dc.description.abstract “The microwave spectra of $N^{14}O_{2}^{16}$ and $N^{15}O^{16}_{2}$ have been assigned and approximate values of the hyperfine interaction parameters have been determined by Bird and $Baird.^{1}$ The determination of accurate values of these parameters requires a least squares fit of all the data because the observed lines are insensitive to several of the parameters. By combining the $N^{14}O_{2}^{16}$, the $N^{15}O_{2}^{16}$, and $N^{14} O^{16}O^{18}$ (obtained in the course of the present investigation) microwave frequencies in such a fit, fairly accurate values of all the hyperfine interaction parameters have been obtained. The interpretation of these parameters in terms of the electronic structure of the molecule will be briefly discussed. In addition the Stark, effect of the $8_{08}\rightarrow 7_{17}$ transition of $N^{14}O^{16}_{2}$ has been partially resolved. The dipole moment of $NO_{2}$ can be estimated from this.” en_US dc.format.extent 104193 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title DETERMINATION OF THE HYPERFINE INTERACTION PARAMETERS OF NITROGEN DIOXIDE FROM THE MICROWAVE $SPECTRUM^{*}$ en_US dc.type article en_US
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