THE MICROWAVE SPECTRUM AND QUADRUPOLE COUPLING  CONSTANTS OF 2--$BROMOPROPANE^{*}$

dc.creator	Tobiason, F. L.	en_US
dc.creator	Schwendeman, R. H.	en_US
dc.date.accessioned	2006-06-15T13:11:11Z
dc.date.available	2006-06-15T13:11:11Z
dc.date.issued	1963	en_US
dc.identifier	1963-C-1	en_US
dc.identifier.uri	http://hdl.handle.net/1811/8190
dc.description	$^{*}$Supported by a grant from the Petroleum Research Fund Administered by the American Chemical Society and a Frederick G. Cottrell grant from the Research Corporation.	en_US
dc.description	Author Institution: Kedzie Chemical Laboratory, Michigan Stale University	en_US
dc.description.abstract	“The microwave spectra of $(CH_{3})_{2}CHBr^{79},(CH_{3})_{2}CHBr^{31}$, and $(CH_{3})_{2} C^{13} HBr^{79}$ have been examined and a number of rotational transitions assigned. Preliminary values of the rotational constants for the bromine-79 species are A =8030.6 Mc. B=2917.67 Mc, and C=2295.38 Mc. The CBr bond distance computed by the substitution method is 1.902 {\AA}. The quadrupole coupling constants along the principal inertial axes, as obtained by first-order calculations, are $\chi_{aa} = 477.9\;MC\;,\chi_{bb} = -262.9$ Mc, and $\chi_{ee} = -215.1$ Mc for the Br-79 species. Progress toward correcting for evident second-order quadrupole effects in the hyperfine splittings will be discussed.”	en_US
dc.format.extent	89439 bytes
dc.format.mimetype	image/jpeg
dc.language.iso	English	en_US
dc.publisher	Ohio State University	en_US
dc.title	THE MICROWAVE SPECTRUM AND QUADRUPOLE COUPLING CONSTANTS OF 2--$BROMOPROPANE^{*}$	en_US
dc.type	article	en_US