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dc.creatorGora, Edwin K.en_US
dc.date.accessioned2006-06-15T13:10:20Z
dc.date.available2006-06-15T13:10:20Z
dc.date.issued1961en_US
dc.identifier1961-Q-2en_US
dc.identifier.urihttp://hdl.handle.net/1811/8149
dc.description$^{*}$ Supported by the Geophysics Research Directorate, Air Force Cambridge Research Laboratories. $^{1}$ A. Danti and R.C. Lord. J. Chem. Phys. 30, 1310 (1959). $^{2}$ H.A. Gebbie, Unpublished.en_US
dc.descriptionAuthor Institution: Physics Department, Providence Collegeen_US
dc.description.abstractRecent experimental investigations of the far infrared rotational spectra. of ozone and sulfur $dioxide^{1,2}$ suggested a theoretical study of these spectra. This study revealed the appearance of groups of high J-low K lines, either of the type $R_{R}(J_{0}),\; R_{P}((J-1)_{2}),\;R_{R} ((J-2)_{2}),\;R_{p}((J-3)_{4})\ldots$ $orR_{P}\;(J)1),\;R_{R}\;((J-1)_{1}),\;R_{P}\;((J-2)_{3}),\;R_{R}\;((J-3)_{3})\ldots$ within surprisingly narrow frequency intervals. The width of these intervals decreases, in general, with increasing J. In the $SO_{2}$ spectrum, for instance, the number of lines of such multiplets within frequency intervals of width $0.1 cm^{-1}$ is two for $J \geq 32$, three fur $J \geq 45$, four for $J \geq 58$, etc. Some of the peaks in Gebbie’s absorption curves appear to be due. to such multiples. The formation of such multiplets was not expected An attempt to understand the reason for their occurence led to the development of algebraic approximation procedures for the evaluation of high J-low K lines. Some of the formulas thus obtained are surprisingly simple, and might prove useful in the interpretation of experimental results. Sets of such formulas for high J-low K rigid rotor energy levels, centrifugal distortion corrections, and line strengths are in preparation.en_US
dc.format.extent122892 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleHIGH J-LOW K APPROXIMATION PROCEDURES IN ASYMMETRIC ROTOR $THEORY^{*}$en_US
dc.typearticleen_US


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