INFLUENCE OF VIBRATIONS ON MOLECULAR STRUCTURE DETERMINATIONS II THE ``QUANTUM DEFECT'' AND SIMILAR EFFECTS

dc.creator	Laurie, Victor W.	en_US
dc.creator	Herschbach, Dudley R.	en_US
dc.date.accessioned	2006-06-15T13:07:45Z
dc.date.available	2006-06-15T13:07:45Z
dc.date.issued	1960	en_US
dc.identifier	1960-R-2	en_US
dc.identifier.uri	http://hdl.handle.net/1811/8027
dc.description	$^{*}$National Science Foundation Postdoctoral Fellow. 1959-60. $^{\dagger}$RAlfred P. Sloan Fellow.	en_US
dc.description	Author Institution: Department of Chemistry, University of California Berkeley	en_US
dc.description.abstract	“The vibrations of a molecule cause terms to appear in the expressions for spectroscopic effective moments of inertia which do not obey the relations fulfilled by ordinary moments of inertia. One familiar example is the fact that $I^{o}_{c}-I^{o}_{a}-I^{o}_{b} \pm 0$ for planar molecules, resulting in the quantum defect.” Nevertheless, the ordinary relations are often used in determining molecular structures. In this way errors and inconsistencies are introduced into the parameters. A discussion of these errors and some ways of compensating for them will be given. Particular attention will be given to the ``quantum defect’’ and related effects.”	en_US
dc.format.extent	83174 bytes
dc.format.mimetype	image/jpeg
dc.language.iso	English	en_US
dc.publisher	Ohio State University	en_US
dc.title	INFLUENCE OF VIBRATIONS ON MOLECULAR STRUCTURE DETERMINATIONS II THE ``QUANTUM DEFECT'' AND SIMILAR EFFECTS	en_US
dc.type	article	en_US