dc.creator Laurie, Victor W. en_US dc.creator Herschbach, Dudley R. en_US dc.date.accessioned 2006-06-15T13:07:45Z dc.date.available 2006-06-15T13:07:45Z dc.date.issued 1960 en_US dc.identifier 1960-R-2 en_US dc.identifier.uri http://hdl.handle.net/1811/8027 dc.description $^{*}$National Science Foundation Postdoctoral Fellow. 1959-60. $^{\dagger}$RAlfred P. Sloan Fellow. en_US dc.description Author Institution: Department of Chemistry, University of California Berkeley en_US dc.description.abstract “The vibrations of a molecule cause terms to appear in the expressions for spectroscopic effective moments of inertia which do not obey the relations fulfilled by ordinary moments of inertia. One familiar example is the fact that $I^{o}_{c}-I^{o}_{a}-I^{o}_{b} \pm 0$ for planar molecules, resulting in the quantum defect.” Nevertheless, the ordinary relations are often used in determining molecular structures. In this way errors and inconsistencies are introduced into the parameters. A discussion of these errors and some ways of compensating for them will be given. Particular attention will be given to the quantum defect’’ and related effects.” en_US dc.format.extent 83174 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title INFLUENCE OF VIBRATIONS ON MOLECULAR STRUCTURE DETERMINATIONS II THE QUANTUM DEFECT'' AND SIMILAR EFFECTS en_US dc.type article en_US
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