dc.creator Krishna, V. G. en_US dc.creator Goodman, Lionel en_US dc.date.accessioned 2006-06-15T13:06:07Z dc.date.available 2006-06-15T13:06:07Z dc.date.issued 1960 en_US dc.identifier 1960-E-9 en_US dc.identifier.uri http://hdl.handle.net/1811/7948 dc.description Author Institution: Whitmore Chemical Laboratory, The Pennsylvania a State University en_US dc.description.abstract The $(n \to \pi^{*})$ $T\to S$ Spectra of pyrazine has been measured at. $77^\circ K$ in hydrocarbon and EPA glasses. A comparison with the absorption $(S\to S^{1})$ data in the same media at $77^\circ K$ indicates the importance of the Franck-Condon principle in the Solvent shift. It is suggested that the n orbitals expand on $n \to \pi^{*}$ emission and a Franck-Condon Strain results from this expansion. The role of this Franck-Condon Strain on $n \to \pi^{*}$ transitions in general will be discussed. The determination of the polarization of the $T\to S$ Spectra of pyrazine is in progress and will be reported. en_US dc.format.extent 65979 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title SOLVENT EFFECTS IN THE $(n \to \pi^{*}) (T\to S)$ EMISSION SPECTRUM OF PYRAZINE en_US dc.type article en_US
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