SOLVENT EFFECTS IN THE $(n \to \pi^{*}) (T\to S)$ EMISSION SPECTRUM OF PYRAZINE
dc.creator | Krishna, V. G. | en_US |
dc.creator | Goodman, Lionel | en_US |
dc.date.accessioned | 2006-06-15T13:06:07Z | |
dc.date.available | 2006-06-15T13:06:07Z | |
dc.date.issued | 1960 | en_US |
dc.identifier | 1960-E-9 | en_US |
dc.identifier.uri | http://hdl.handle.net/1811/7948 | |
dc.description | Author Institution: Whitmore Chemical Laboratory, The Pennsylvania a State University | en_US |
dc.description.abstract | The $(n \to \pi^{*})$ $T\to S$ Spectra of pyrazine has been measured at. $77^\circ K$ in hydrocarbon and EPA glasses. A comparison with the absorption $(S\to S^{1})$ data in the same media at $77^\circ K$ indicates the importance of the Franck-Condon principle in the Solvent shift. It is suggested that the n orbitals expand on $n \to \pi^{*}$ emission and a Franck-Condon Strain results from this expansion. The role of this Franck-Condon Strain on $n \to \pi^{*}$ transitions in general will be discussed. The determination of the polarization of the $T\to S$ Spectra of pyrazine is in progress and will be reported. | en_US |
dc.format.extent | 65979 bytes | |
dc.format.mimetype | image/jpeg | |
dc.language.iso | English | en_US |
dc.publisher | Ohio State University | en_US |
dc.title | SOLVENT EFFECTS IN THE $(n \to \pi^{*}) (T\to S)$ EMISSION SPECTRUM OF PYRAZINE | en_US |
dc.type | article | en_US |
Files in this item
Items in Knowledge Bank are protected by copyright, with all rights reserved, unless otherwise indicated.