dc.creator Hisatsune, I. C. en_US dc.creator Jayadevappa, E. S. en_US dc.date.accessioned 2006-06-15T12:56:41Z dc.date.available 2006-06-15T12:56:41Z dc.date.issued 1959 en_US dc.identifier 1959-M-6 en_US dc.identifier.uri http://hdl.handle.net/1811/7894 dc.description $^{*}$ Financed by a Frederick Gardner Cottrell Grant from the Research Corporation, 1957-9. en_US dc.description Author Institution: Department of Chemistry, Kansas State University en_US dc.description.abstract In order to test the feasibility of measuring infrared intensities of substances in the liquid phase, the intensities of the infrared absorption bands in benzene have been investigated. In the pure liquid, the intensities of all four all four fundamentals: have been measured. Furthermore, the intensities of the out-of-plane C-H bending vibration has been measured in cyclohexane, 2, 2, 4-trimethyl pentane, methyl formate, and ethyl propionate solutions as a function of mole fractions of benzene The effect of iodine on this intensity has also been investigated in the most dilute simple of each of these solutions. The intensity of this fundamental band was found to be always greater in the solution than in the pure liquid. Furthermore, these solution values appear to approach a common limiting value when the mole fraction of benzene was small, even though the concentration dependences were different. These data suggest that appreciable intermolecular interactions occur in the condensed phases and that intensity measurements in these phases may be a method of investigating such interactions. en_US dc.format.extent 110762 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title VIBRATIONAL INTENSITIES OF BENZENE IN THE CONDENSED $PHASE^{*}$ en_US dc.type article en_US
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