Show simple item record

dc.creatorLiehr, Andrew D.en_US
dc.date.accessioned2006-06-15T12:55:27Z
dc.date.available2006-06-15T12:55:27Z
dc.date.issued1959en_US
dc.identifier1959-F-1en_US
dc.identifier.urihttp://hdl.handle.net/1811/7843
dc.descriptionAuthor Institution: Bell Telephone Laboratories, Inc.en_US
dc.description.abstractIf ionic spin-orbital forces are weak, electronic motion in inorganic complexes are governed primarily by the electrostatic coercions of the surrounding ligands, whilst the presence of feeble coulombic directives, but robust spin-orbit correlations, dictates electronic trajectories which are only slightly modified over those characteristic of the free ion. Electronic itineraries of both types have been exhaustively discussed, in the past thirty years, within the framework of the Bethe-Kramers-Van Vleck theory of crystalline fields. However, the rather more esoteric situation in which the spin-orbital and addend field potentials are of comparable magnitude does not seem to have received as thorough a consideration. In this report an account will be given of the optical and magnetic properties expected of $d^{n}$, $(n=1, 9)$, molecular systems, in several geometries, which exhibit equi-energetic spin-orbital and augend field interactions, and will be applied, where observational data is extant, to the transition metal complexes of the third and fourth group. An experimental prospectus is outlined in the hope that such will stimulate future research into this somewhat neglected domain.en_US
dc.format.extent101403 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleSPECTRO-- AND MAGNETO-CHEMISTRY OF AU(II) AND W(V) COMPLEXES AND THEIR HOMOLOGUESen_US
dc.typearticleen_US


Files in this item

Thumbnail

Items in Knowledge Bank are protected by copyright, with all rights reserved, unless otherwise indicated.

This item appears in the following Collection(s)

Show simple item record