dc.creator Fletcher, W. H. en_US dc.creator Bailey, C. E. en_US dc.date.accessioned 2006-06-15T12:54:54Z dc.date.available 2006-06-15T12:54:54Z dc.date.issued 1959 en_US dc.identifier 1959-C-3 en_US dc.identifier.uri http://hdl.handle.net/1811/7820 dc.description $^{*}$ Supported by Office of Ordnance Research, U. S. Army. en_US dc.description Author Institution: Department of Chemistry, The University of Tennessee en_US dc.description.abstract The orbital valency force field with inclusion of van der Waals repulsion terms has been applied to allene, ketene and diazomethane, and the application of this field to ethylene has been re-examined. Correlations among these molecules is generally very good. The van der Waals repulsion are adequate to account for the off-diagonal F matrix elements except in the case of diazomethane. The frequencies for $CH_{2} N_{2}$ and $CD_{2}N_{2}$ can be explained only if some negative off-diagonal elements are employed and this appears to be a result of a direct attraction between the hydrogens and the terminal nitrogen of the molecule. en_US dc.format.extent 75694 bytes dc.format.mimetype image/jpeg dc.language.iso en en_US dc.publisher Ohio State University en_US dc.title THE ORBITAL VALENCY FORCE FIELD IN ALLENE, KETENE AND $DIAZOMETHANE^{*}$ en_US dc.type article en_US
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