Show simple item record

dc.creatorFletcher, W. H.en_US
dc.creatorBailey, C. E.en_US
dc.date.accessioned2006-06-15T12:54:54Z
dc.date.available2006-06-15T12:54:54Z
dc.date.issued1959en_US
dc.identifier1959-C-3en_US
dc.identifier.urihttp://hdl.handle.net/1811/7820
dc.description$^{*}$ Supported by Office of Ordnance Research, U. S. Army.en_US
dc.descriptionAuthor Institution: Department of Chemistry, The University of Tennesseeen_US
dc.description.abstractThe orbital valency force field with inclusion of van der Waals repulsion terms has been applied to allene, ketene and diazomethane, and the application of this field to ethylene has been re-examined. Correlations among these molecules is generally very good. The van der Waals repulsion are adequate to account for the off-diagonal F matrix elements except in the case of diazomethane. The frequencies for $CH_{2} N_{2}$ and $CD_{2}N_{2}$ can be explained only if some negative off-diagonal elements are employed and this appears to be a result of a direct attraction between the hydrogens and the terminal nitrogen of the molecule.en_US
dc.format.extent75694 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoenen_US
dc.publisherOhio State Universityen_US
dc.titleTHE ORBITAL VALENCY FORCE FIELD IN ALLENE, KETENE AND $DIAZOMETHANE^{*}$en_US
dc.typearticleen_US


Files in this item

Thumbnail

Items in Knowledge Bank are protected by copyright, with all rights reserved, unless otherwise indicated.

This item appears in the following Collection(s)

Show simple item record