THE PERPENDICULAR BANDS OF ALLENE AND ALLENE d4

dc.creator	Overend, John	en_US
dc.creator	Crawford, Bryce, Jr.	en_US
dc.date.accessioned	2006-06-15T12:53:54Z
dc.date.available	2006-06-15T12:53:54Z
dc.date.issued	1958	en_US
dc.identifier	1958-N-04	en_US
dc.identifier.uri	http://hdl.handle.net/1811/7791
dc.description	$^{1}$B. P. Stoicheff, Can. J. Phys. 33, 811 (1956).	en_US
dc.description	Author Institution: Department of Chemistry, University of Minnesota, Minneapolis, MN	en_US
dc.description.abstract	The distribution of intensity in the perpendicular bands of allene has been examined, taking into account the effect of the Coriolis interaction between the degenerate levels $\nu_{2}$ and $\nu_{10}$. The results indicate that in all the perpendicular bands of allene and allene-$d_{4}$ the $^{R}{Q}_{0}$ branch lies on a line which divides the band into two equal (or very nearly equal) areas. This has been used as a criterion for a new rotational assignment of these bands and the rotational constants A and $\zeta$ have been re-evaluated. The present A values, together with $Stoicheff’s^{1}$ B values indicate that the CH bond length is 1.061 A and the HCH angle $116^{\circ}$.	en_US
dc.format.extent	74214 bytes
dc.format.mimetype	image/jpeg
dc.language.iso	en	en_US
dc.publisher	Ohio State University	en_US
dc.title	THE PERPENDICULAR BANDS OF ALLENE AND ALLENE d4	en_US
dc.type	article	en_US