dc.creator Overend, John en_US dc.creator Crawford, Bryce, Jr. en_US dc.date.accessioned 2006-06-15T12:53:54Z dc.date.available 2006-06-15T12:53:54Z dc.date.issued 1958 en_US dc.identifier 1958-N-04 en_US dc.identifier.uri http://hdl.handle.net/1811/7791 dc.description $^{1}$B. P. Stoicheff, Can. J. Phys. 33, 811 (1956). en_US dc.description Author Institution: Department of Chemistry, University of Minnesota, Minneapolis, MN en_US dc.description.abstract The distribution of intensity in the perpendicular bands of allene has been examined, taking into account the effect of the Coriolis interaction between the degenerate levels $\nu_{2}$ and $\nu_{10}$. The results indicate that in all the perpendicular bands of allene and allene-$d_{4}$ the $^{R}{Q}_{0}$ branch lies on a line which divides the band into two equal (or very nearly equal) areas. This has been used as a criterion for a new rotational assignment of these bands and the rotational constants A and $\zeta$ have been re-evaluated. The present A values, together with $Stoicheff’s^{1}$ B values indicate that the CH bond length is 1.061 A and the HCH angle $116^{\circ}$. en_US dc.format.extent 74214 bytes dc.format.mimetype image/jpeg dc.language.iso en en_US dc.publisher Ohio State University en_US dc.title THE PERPENDICULAR BANDS OF ALLENE AND ALLENE d4 en_US dc.type article en_US
﻿