ELECTRONIC INTERACTIONS IN PHENYL ACETATES AND ACETANILIDES
|dc.creator||Freedman, H. H.||en_US|
|dc.description||Author Institution: Eastern Research Laboratory, The Dow Chemical Company||en_US|
|dc.description.abstract||“The relative importance of an inductive vs. a resonance mechanism for the high carbonyl absorption frequency of phenyl acetate and acetanilide has been investigated. A study of the C-O frequency shifts in their meta and para-subtituted derivatives clearly shows that the inductive mechanism is responsible for the frequency shift in phenyl acetate, but a resonance mechanism is more appropriate in the acetanilides. This is supported by a study of their respective Stuart-Briegleb molecular models which, on the basis of steric inhibition of resonance due to lack of coplanarity within the molecule, indicates that a resonance mechanism is relatively unimportant in phenyl acetate.”||en_US|
|dc.publisher||Ohio State University||en_US|
|dc.title||ELECTRONIC INTERACTIONS IN PHENYL ACETATES AND ACETANILIDES||en_US|
Files in this item
Items in Knowledge Bank are protected by copyright, with all rights reserved, unless otherwise indicated.