ELECTRONIC INTERACTIONS IN PHENYL ACETATES AND ACETANILIDES

dc.creator	Freedman, H. H.	en_US
dc.date.accessioned	2006-06-15T12:53:10Z
dc.date.available	2006-06-15T12:53:10Z
dc.date.issued	1958	en_US
dc.identifier	1958-I-10	en_US
dc.identifier.uri	http://hdl.handle.net/1811/7759
dc.description	Author Institution: Eastern Research Laboratory, The Dow Chemical Company	en_US
dc.description.abstract	“The relative importance of an inductive vs. a resonance mechanism for the high carbonyl absorption frequency of phenyl acetate and acetanilide has been investigated. A study of the C-O frequency shifts in their meta and para-subtituted derivatives clearly shows that the inductive mechanism is responsible for the frequency shift in phenyl acetate, but a resonance mechanism is more appropriate in the acetanilides. This is supported by a study of their respective Stuart-Briegleb molecular models which, on the basis of steric inhibition of resonance due to lack of coplanarity within the molecule, indicates that a resonance mechanism is relatively unimportant in phenyl acetate.”	en_US
dc.format.extent	69096 bytes
dc.format.mimetype	image/jpeg
dc.language.iso	English	en_US
dc.publisher	Ohio State University	en_US
dc.title	ELECTRONIC INTERACTIONS IN PHENYL ACETATES AND ACETANILIDES	en_US
dc.type	article	en_US