ELECTRONIC INTERACTIONS IN PHENYL ACETATES AND ACETANILIDES
dc.creator | Freedman, H. H. | en_US |
dc.date.accessioned | 2006-06-15T12:53:10Z | |
dc.date.available | 2006-06-15T12:53:10Z | |
dc.date.issued | 1958 | en_US |
dc.identifier | 1958-I-10 | en_US |
dc.identifier.uri | http://hdl.handle.net/1811/7759 | |
dc.description | Author Institution: Eastern Research Laboratory, The Dow Chemical Company | en_US |
dc.description.abstract | “The relative importance of an inductive vs. a resonance mechanism for the high carbonyl absorption frequency of phenyl acetate and acetanilide has been investigated. A study of the C-O frequency shifts in their meta and para-subtituted derivatives clearly shows that the inductive mechanism is responsible for the frequency shift in phenyl acetate, but a resonance mechanism is more appropriate in the acetanilides. This is supported by a study of their respective Stuart-Briegleb molecular models which, on the basis of steric inhibition of resonance due to lack of coplanarity within the molecule, indicates that a resonance mechanism is relatively unimportant in phenyl acetate.” | en_US |
dc.format.extent | 69096 bytes | |
dc.format.mimetype | image/jpeg | |
dc.language.iso | English | en_US |
dc.publisher | Ohio State University | en_US |
dc.title | ELECTRONIC INTERACTIONS IN PHENYL ACETATES AND ACETANILIDES | en_US |
dc.type | article | en_US |
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