Show simple item record

dc.creatorTurrell, George C.en_US
dc.creatorHansen, Karl H.en_US
dc.date.accessioned2006-06-15T12:53:08Z
dc.date.available2006-06-15T12:53:08Z
dc.date.issued1958en_US
dc.identifier1958-I-08en_US
dc.identifier.urihttp://hdl.handle.net/1811/7757
dc.description$^{\dagger}$Present address: Frick Chemical Laboratory, Princeton University, Princeton, New Jersey.en_US
dc.descriptionAuthor Institution: Meteall Research Laboratory, Brown Universityen_US
dc.description.abstract“The infrared spectra of $Ti(urea)_{6}I_{2}, [V(urea)_{6}]I_{3}$ and $[Cr(urea)_{6}]I_{3}$ were obtained from Nujol mulls and KBr pellets over the range $4000 cm^{-1}$ to $400 cm^{-1}$ using $CaF_{2}$, $NaCl$ and KBr prisms. The spectrum of urea was rerun over the same range for comparison. A force-constant calculation for the skeletal skeletal of moxles of urea was carried out using a potential function of the Urey-Bradley type. Assignments of the observed, bands in the complexes were made on the basis of the previously established assignments for urea. Force-constant calculations were made for the urea ligands again using the Urey-Bradley potential. Thus the frequency shifts observed in the spectra of the complexes were interpreted in terms of an effective force constant for the metal-oxygen bonds and changes in the urea skeletal force constants.”en_US
dc.format.extent84627 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleINFRARED SPECTRA OF THE HEXAUREA COMPLEXES OF $Ti^{{III}}$, $V^{{III}}$ AND $Cr^{III}$en_US
dc.typearticleen_US


Files in this item

Thumbnail

Items in Knowledge Bank are protected by copyright, with all rights reserved, unless otherwise indicated.

This item appears in the following Collection(s)

Show simple item record