dc.creator Turrell, George C. en_US dc.creator Hansen, Karl H. en_US dc.date.accessioned 2006-06-15T12:53:08Z dc.date.available 2006-06-15T12:53:08Z dc.date.issued 1958 en_US dc.identifier 1958-I-08 en_US dc.identifier.uri http://hdl.handle.net/1811/7757 dc.description $^{\dagger}$Present address: Frick Chemical Laboratory, Princeton University, Princeton, New Jersey. en_US dc.description Author Institution: Meteall Research Laboratory, Brown University en_US dc.description.abstract “The infrared spectra of $Ti(urea)_{6}I_{2}, [V(urea)_{6}]I_{3}$ and $[Cr(urea)_{6}]I_{3}$ were obtained from Nujol mulls and KBr pellets over the range $4000 cm^{-1}$ to $400 cm^{-1}$ using $CaF_{2}$, $NaCl$ and KBr prisms. The spectrum of urea was rerun over the same range for comparison. A force-constant calculation for the skeletal skeletal of moxles of urea was carried out using a potential function of the Urey-Bradley type. Assignments of the observed, bands in the complexes were made on the basis of the previously established assignments for urea. Force-constant calculations were made for the urea ligands again using the Urey-Bradley potential. Thus the frequency shifts observed in the spectra of the complexes were interpreted in terms of an effective force constant for the metal-oxygen bonds and changes in the urea skeletal force constants.” en_US dc.format.extent 84627 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title INFRARED SPECTRA OF THE HEXAUREA COMPLEXES OF $Ti^{{III}}$, $V^{{III}}$ AND $Cr^{III}$ en_US dc.type article en_US
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