dc.creator Guenther, A. H. en_US dc.creator Wiggins, T. A. en_US dc.creator Rank, D. H. en_US dc.date.accessioned 2006-06-15T12:50:35Z dc.date.available 2006-06-15T12:50:35Z dc.date.issued 1957 en_US dc.identifier 1957-H-7 en_US dc.identifier.uri http://hdl.handle.net/1811/7643 dc.description $^{*}$This Research was assisted by support from Contract Non r-656(12) NR 019-101 of the U. S. Office of Naval Research. $^{1}$H. C. Allen. Jr., E. K. Plyler and L. R. Blaine. JACS 78, 48 43 (1956). $^{2}$H. H. Nielsen. Phys. Rev. 77, 130 (1950). en_US dc.description Author Institution: Spectroscopy Laboratory, The Pennsylvania State University en_US dc.description.abstract “The $3v_{1}$ and $v_{2}+3v_{1}-v_{2}$ bands at 4566.810 and $4547.464 cm^{-1}$ respectively, were analyzed and $B_{000}, \alpha_{2}$ and $\alpha_{2}$ evaluated. By using $\alpha_{1}$ as determined from $B^{\prime}-B^{\prime}^{\prime}$ of the $2v_{1}+v_{3}$ band as measured by Allen. Plyler and $Blaine,^{1}$ $B_{e}$ was calculated. The values ${r}_{o}=1.554 _{b} A$ and $r_{e} = 1.553$ are in excellent agreement with the $C- S$ distance in OCS as measured by microwave methods. The R branch of the $3v_{2}$ band, which covers less than $5.5 cm^{-1}$, exhibits a Fortrat parabola such that R(100) is adjacent to R(0). It was possible to resolve all but seven lines of this branch. The value of $q^{\prime}^{\prime}$$(6.7\times 10^{-5}) cm^{-1}) the splitting constant of the v_{2} state, is within experimental error of the value q^{\prime}^{\prime}=7.7\times 10^{-5} as calculated by Nielsen’s Theory.^{2} From the band origins measured in this investigation and origins of other bands previously determined by other investigations, a complete set of \omega’s and anharmonicity constants are evaluated for CS_{2}^{12}. The molecular constants determined are in cm^{-1}:” en_US dc.format.extent 120710 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title THE INTERNUCLEAR DISTANCE AND / TYPE DOUBLING IN CS^{32}_{2}$$^{*}$ en_US dc.type article en_US
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