Show simple item record

dc.creatorGallup, G. A.en_US
dc.date.accessioned2006-06-15T12:48:44Z
dc.date.available2006-06-15T12:48:44Z
dc.date.issued1956en_US
dc.identifier1956-Q-5en_US
dc.identifier.urihttp://hdl.handle.net/1811/7557
dc.descriptionAuthor Institution: Department of Chemistry and Chemical Engineering, University of Nebraskaen_US
dc.description.abstractMeasurements of the infrared active fundamental of liquid $CS_{2}$ ($1510 cm^{-1}$) indicate as is to be expected that there is a breakdown of the gaseous rotational selection rules. The general aspect of the band is Gaussian. However, deviations from the Gaussian shape strongly suggest that there are a number of sub-bands or branches on either side of the central maximum. As many as 8 of these branches are visible. Theoretical considerations using simple potential functions indicate that the selection rules for a parallel band of a linear molecule in a liquid could be $\Delta{M}= \O$; $AJ=O,\pm 2, \pm 4$,.... and $\Delta{M}=\pm 1$; $AJ=\pm 1$ with perhaps the addition of $\pm 3, \pm 5$,.... An interpretation of the band shape in terms of these selection rules and potential functions allows an estimate of the force tending to hold the molecule in a given direction in the liquid.en_US
dc.format.extent83742 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleTHE BAND SHAPE OF $\nu_{3}$ OF LIQUID $CS_{2}$en_US
dc.typearticleen_US


Files in this item

Thumbnail

Items in Knowledge Bank are protected by copyright, with all rights reserved, unless otherwise indicated.

This item appears in the following Collection(s)

Show simple item record